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Re-hydrating the battery modules.

Discussion in 'Gen 2 Prius Technical Discussion' started by Britprius, May 6, 2015.

  1. Britprius

    Britprius Senior Member

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    Did you come across "I will call it stuck valve syndrome" in your pressure test where the initial break pressure was higher than 80 psi? This pressure is difficult to read because it reaches a point where the valve is forced open and the pressure suddenly drops to a steady 80 psi, and cannot be repeated.
    Obviously this phenomena will not apply to all modules.


    John
     
    #61 Britprius, May 10, 2015
    Last edited: May 10, 2015
  2. royfrontenac

    royfrontenac Member

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    Hi Brad - Your input is very valuable keep up the good work, I just noted the screws that are in the battery picture are in line with the walls of the batteries, some are on a slant and may allow water in and others may not. If some cells got more water then others they could overpower a weaker cell and cause a reversal which would cause the venting from overheating that cell or cells. This is only speculation but may have been the reason for the vent.

    Roy from Canada Gen 1 and 2 Battery modules 001.JPG Gen 1 and 2 Battery modules 001.JPG Gen 1 and 2 Battery modules 001.JPG Gen 1 and 2 Battery modules 001.JPG








    r

     
    #62 royfrontenac, May 10, 2015
    Last edited: May 12, 2015
  3. Britprius

    Britprius Senior Member

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    Roy from memory of seeing those picture before. The screws were used to connect to the cell interconnects for reading individual cell voltages as marked on the face of the cells, and not for topping up purposes.

    John

    Roy your information on the required amount of liquid required to fill cells from dry is invaluable. I have done measurements on the re-hydrated modules, and can confirm the fluid I added does not cover the top of the cells. I believe why I am still registering full capacity "electrically" is because the cell plates and separators being tightly packed are exhibiting a capillary effect between the plates with the separators absorbing the fluid. This will have the effect of wetting all the area of plates. All that is required for full cell capacity.
    I will now look at altering the angle of the module for final filling to enable the fluid to reach the 20ml level. Where modules have not completely dried out as in your instance this should give a level close to the self set target of 25% of the void above the plates.

    John
     
    #63 Britprius, May 10, 2015
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  4. ChapmanF

    ChapmanF Senior Member

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    Pressure transducer wired to a chart recorder for that retro vibe, or an A/D input to a computer logging rapid samples otherwise. :)

    This Dwyer seems to be offered in 17-4PH or 316 L for the wetted surfaces ... according to this chart the 316 appears better for KOH (though one would probably set it up so it sees nothing but air anyway).

    -Chap
     
  5. a_triant

    a_triant Member

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    So that's mean the method how to fill from 1st post will not cover the top of plates and need search for another method right?
    Then maybe will need to make the offset of second hole same like in the first hole so when the module laying on it side it can be filled more before the liquid will go out from hole, but that's again maybe will be not enough to cover the plates... :confused:
    maybe then need to try a different angles while filling them

    Looks like the easiest way is with 6 holes to fill them all above the plates and at same level.

    Alex.
    Thanks.
     
    #65 a_triant, May 10, 2015
    Last edited: May 10, 2015
  6. Britprius

    Britprius Senior Member

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    Tilting the module backwards slightly by raising the side that we fill from will allow a higher level of fluid to be obtained. Raising the level of the drain hole above the center line of the module will cause an air lock and stop the cells being filled evenly.
    In use it is only required that the plates are whetted for operation in the same way that AGM batteries are. When working out the filling system being able to adjust the amount of fluid added set automatically by the filling angle is one of the things I took into consideration. Do not alter the height of the holes these are based on the position of the transfer holes between the cells.
    It is through additional information and indeed materials being supplied by other PC members like Roy, and Hybridbatt that fine tuning of the system can be accomplished for the good of all.
    When I have found the angle to be used to fill above the cell plates I will edit my first post accordingly to give details.

    John
     
    #66 Britprius, May 10, 2015
    Last edited: May 10, 2015
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  7. royfrontenac

    royfrontenac Member

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    I will try again

    Hi Brad - Your input is very valuable keep up the good work, I just noted the screws that are in your battery picture are in line with the walls of the batteries, some are on a slant and may allow water in and others may not. If some cells got more water then others they could overpower a weaker cell and cause a reversal which would cause the venting from overheating that cell or cells. This is only speculation but may have been the reason for the vent.
    That makes sense John, this method of measuring the individual cell voltages is very good and I should have understood their purpose.

    to ---- Brad_ sorry I brought up this observation, disregard my post.

    Roy
     

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  8. Britprius

    Britprius Senior Member

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    Roy I have been looking at how much to raise the angle of the module to add the extra fluid needed. It looks like raising the front of the module where holes were drilled about 1 inch on the final fill will give the required result. I will not be able to finalize this until Tuesday because I am away all day tomorrow, but as soon as I have the results I will post them.
    The input coming in from everyone is helpful and time saving.
    I had considered most things when when working on this. I was unable to test every possibility due to the lack of enough modules. However again must thank Hybridbatt for his very generous contribution to this project without which it would not have appeared, and all that are providing information including safety concerns that allow us to take the precautions to avoid accidents.
    Thank you again everyone.

    John (Britprius)
     
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  9. royfrontenac

    royfrontenac Member

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    Hi John - I have made a spare Gen1 battery using Gen 2 modules -installed it a while back -- as long as I drive it around town it has lasted about a month with no triangle of death code for the battery - however I recently took a 200 mile trip and the code for bank #9 ( #17 and #18 modules I think) came up and I had to reset the code 6 times during my trip( I had my computer with techstream with me). I may try to fill the bad modules in place with water or a solution once we have a method to fill the modules in place in the car.I monitored the battery during the trip and found that the code appeared after going up a steep hill and going down the other side of the hill the code came up. The load currents on the battery were not above 10 amps and the code appeared when the battery was charging on the downside of the hill at 13 to 15 amps. The voltage across modules 17 and 18 rose above the others by at least 1.5 to 2 volts which must have triggered the code.

    Since I now have a spare car, I will use it as a test vechicle. I have the backseat removed so I have ready access to the battery by removing the fan cowing and the battery cover to do the experiments.
     
    #69 royfrontenac, May 10, 2015
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  10. hybridbatt

    hybridbatt Junior Member

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    No John this one did not stick that might be because its a duff module that i have chucked in and out of a box & generally not been bothered how i treat it so i expect it was loosened, i think if it had not been moved out of a pack or treated very gently it would of stuck.

    Richard
     
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  11. Britprius

    Britprius Senior Member

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    The internal resistance on those modules has risen and is why the voltage rises when being charged at 15 amps. It would be interesting to add say 10 ml of water to those cells. Record the resistance in Techstream before filling and check again after a few runs. If it falls significantly you could add another 10 ml if it falls slightly add 10 ml with KOH or Naoh in it and try again. You could do this without resealing the module as in the short term it make no difference to it' opperation.

    John
     
  12. royfrontenac

    royfrontenac Member

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    My other 3 cars have Gen 1 modules in them and they are working OK. It seems it is not how high a discharge capacity the modules have but how close their voltages are under heavy loads and charging. Modules 18 and 19 both had discharge values in the 5500 range with 5 amp discharge conditions before I installed them in the spare battery. My friend gave me some more Gen 2 modules and during our chat he mentioned the newer cars were triggering with as low as a 0.6 volt difference -- making his rebuilding of the batteries more difficult to sell as codes come up more easily.

    Roy
     
  13. Britprius

    Britprius Senior Member

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    Thanks Richard. Was this a gen1 or gen2 module.

    John

    The module pair resistance is more important than capacity. No matter where a low or high capacity module is in the battery makes no difference. the capacity remains the same. With the resistance the module voltages (on load or on charge) will vary along with the resistance of the pair so a high and low resistance pair of modules together will help compensate for each other. I will come back with figures latter.

    John
     
    #73 Britprius, May 10, 2015
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  14. royfrontenac

    royfrontenac Member

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    In one car I have G1 modules that I recycled 3 times(over a year ago) and all 38 were in the 3000 to 3500 discharge range. this car has gone 15000 km and is still running with that battery. It has gone up to 800 km round trip jaunts and never thrown a code. Because this was the first of my 2001 prius purchases and I had no experience with the batteries I thought the battery was in good shape after the recycling. I would not trust that battery to-day ??? However I did use my highvoltage charger/discharger twice in a years period on that battery - this may have have made difference.

    Techstream gives you the resistance of the paired modules (as you know).

    The resistance readings I get in all my cars are usually 18 to 19 micro ohms.

    Bad bank # 9 in the experimental battery is reading 19 , many others in the bank are reading 19 as well.?????

    Once we have developed a method to add solution while battery is in the car I will proceed and test the results as you recommend. I have not made any experiments yet with the spare modules I have. But will do so in a few days as more knowledge accumulates. I wonder if Bob Wilson could join the discussion as he has conducted experiments similar to what we are doing and could also help us along the road.

    Roy
     
    #74 royfrontenac, May 10, 2015
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  15. Britprius

    Britprius Senior Member

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    I private message Bob before embarking on this project as it was his early posts that inspired my efforts, and why I acknowledged his support in the first line of my post.
    He intimated that gaining near new performance from the modules was not the problem, but wished me luck with finding a solution to resealing the cells.
    Bob basically had been working on filling or bonding a plastic or stainless patch over the holes without any great success.
    I had already come up with the idea of threading the holes realizing that the smaller the hole the less area that needs to be sealed, and the less force on a given area.
    A 1 mm dia screw has a surface area of 0.7855 sq mm. 1 sq inch is 645.16 sq mm Force pushing on a 1 sq mm at 80 psi is:-
    80 divided by 645.16 = 0.124 lbs
    Surface area of 1mm dia screw is 0.7855 sq mm X lbs 0.124 = 0.0974 lbs or 1.5584 ozs force on the screw.
    A 1 mm screw also has a thread pitch of 70 per inch giving lots of sealing area within the thread. Even with a top cell thickness of only 4.4 mm this will give just over 12 threads in the hole.

    I then worked on a method of reducing the hole count from 6 to only 2

    John
     
    #75 Britprius, May 10, 2015
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  16. The Inquisitor

    The Inquisitor Junior Member

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    Thank you for all the valuable information Britprius.
     
  17. royfrontenac

    royfrontenac Member

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    Good that you were communicating with Bob and you decided to carry on the process.
     
  18. strawbrad

    strawbrad http://minnesotahybridbatteries.com

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    #78 strawbrad, May 10, 2015
    Last edited: May 10, 2015
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  19. royfrontenac

    royfrontenac Member

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    I read the post by jeffkay and found this paragraph from the post very interesting as it got him 20000 miles of driving ---


    xxx "Small holes are drilled above each well. Boiling distilled water is injected via syringe--30ml each. The boiling water makes the grids or plates more likely to wick up some water. Panasonic used a gel originally but "re-gelling" them would be impossible...

    Stainless steel screws are "self-threaded" right into the case after the water is insjected. I wanted to use some o-rings but got lazy. The screws can be opened in the future should you go to Death Valley once more. As Bob notes, The dissimilar plastic screw interface may leak vapors. But between the main vent opening and the fact that these batteries should not vent under normal conditions, I did not make any big deal over it. I did test melting chunks of a junk case into the holes with a simple soldering iron and it works great but is time consuming. May be the way to go if you are worried about leaks." xxx


    Roy from Canada now ------

    With his method I am going to try to re-hydrate one module installed in the battery of my car that is not performing as well as follows:
    :
    1) Using 3/8 in self tapping stainless steel screws drill into the top of each cell with the screw (using a power drill will make it fast).
    2) Remove the screw (you only need to go down 1/4 inch to thread the hole)
    3) Boil distilled water
    4) Using a syringe marked at 10 mm from the end (so you do not touch the battery below and short it out) and insert 11 ml into each cell
    5) Re-install the six screws
    6) Drive the car and use my mini vic to see the difference in the modules battery voltage and resistance before and after re-hydration.
     
    #79 royfrontenac, May 11, 2015
    Last edited: Jun 13, 2015
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  20. a_triant

    a_triant Member

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    Roy, if you going to do 6 holes then i think better way is like John(Britprius) said in other thread:

    "My intention is also to fill the cell and then draw off any water above the cell plates "the reason for using a plastic tube on the syringe". This will ensure all the cells have the same level of electrolyte at the end of the process.
    As soon as I have found suitable positions to drill I will come back with details."

    or you can do that with syringe needle, since you said before the depth from top to battery plates is 13.49 mm so you can make a mark on needle at 10mm example and with that way you will sure that you will not touch the plates and you will know that every cell you filled equally 3.49mm above the plates.

    Alex.
    Thanks.
     
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