1. Attachments are working again! Check out this thread for more details and to report any other bugs.

traction battery and extra long term storage

Discussion in 'Gen 2 Prius Technical Discussion' started by ozmatt, Sep 30, 2016.

  1. ozmatt

    ozmatt Active Member

    Joined:
    Nov 27, 2015
    571
    234
    0
    Location:
    australia
    Vehicle:
    2010 Prius
    Model:
    One
    I know this has been covered before but a long time ago and no real definite answer in any previous threads.

    extended periods of hv battery storage (years) ...

    If traction battery sits in storage unused for multiple years will the modules self discharge past a point of return? I understand they can sit almost indefinitely "if stored above 7.2v" I understand the pack needs to be re-charged before its put back to use, at some stage (months/years) even good modules must self-discharge under 7.2v and eventually reverse?

    So battery gurus, has anyone let a hv battery pack sit in storage for multiple years and if so what happened did it survive?

    Matt
     
  2. WilDavis

    WilDavis Senior Member

    Joined:
    Feb 4, 2014
    2,489
    2,153
    49
    Location:
    Top RH Corner of RH Coast on L side of The Pond
    Vehicle:
    2009 Prius
    Model:
    II
    My advice to you would be to read all you can about Grid Charging (use search to find Grid, Charging, Prolong). Also, you might find this link to be useful: Prolong Battery Systems. Extending the life of your hybrid. – Hybrid Automotive
    - Good luck!
     
    jeff652 likes this.
  3. fotomoto

    fotomoto Senior Member

    Joined:
    Apr 22, 2009
    5,597
    3,771
    0
    Location:
    So. Texas
    Vehicle:
    Other Hybrid
    ozmatt likes this.
  4. dolj

    dolj Senior Member

    Joined:
    May 14, 2012
    7,510
    3,773
    0
    Location:
    Wellington, New Zealand
    Vehicle:
    2007 Prius
    Model:
    N/A
    As I understand it, a cell (or cells) within a module will only reverse if the module is out of balance. A balanced module (where all cells self-discharge rate at the same rate) will self-discharge to 0 V and sit there for a long time. The uneven discharge rate between cells tends to get greater over time, hence an older battery (with a lot of charge/discharge cycles on it) is more at risk of damage due to self-discharge when compare to a new battery (or an older battery with no (or few) charge/discharge cycles.

    That is at least the theory as I understand it. I'm sure someone will chip in if I'm wrong.
     
  5. ozmatt

    ozmatt Active Member

    Joined:
    Nov 27, 2015
    571
    234
    0
    Location:
    australia
    Vehicle:
    2010 Prius
    Model:
    One
    hi thanks for your reply, yes I have a grid charger but some are saying these NIMH batteries are best stored almost completely discharged others argue that, I don't want to go back to a pack in 2 years and every module is shot because I did not store it properly.

    yes that's one way they can reverse but I believe they can also start to reverse if they self discharge too much

    would love to hear from anyone that has stored batteries for a few years
     
  6. ozmatt

    ozmatt Active Member

    Joined:
    Nov 27, 2015
    571
    234
    0
    Location:
    australia
    Vehicle:
    2010 Prius
    Model:
    One
  7. tpenny67

    tpenny67 Active Member

    Joined:
    Jun 14, 2014
    464
    402
    0
    Location:
    Massachusetts, USA
    Vehicle:
    2014 Prius
    Model:
    Two
    Cell reversal happens when some cells in a pack are empty, and energy is drawn from the pack. The cells that still have energy force current through the empty cells and charge them in reverse. If you charge a pack before drawing any energy from it, cell reversal shouldn't be a problem. Also, if you have a single cell (such as the battery in your cell phone) then it's impossible to reverse it.

    The other issue (if I remember correctly) is that an empty cell can have a non-zero voltage. In other words, when the cell is newly assembled before any charge is put into it, the chemistry gives it a baseline voltage. Because it has voltage you can draw power from it, but this will damage the cell.

    Long story short, if a battery has been in storage for a while, it's probably best to try putting some charge into it first before trying to assess its health.
     
  8. ozmatt

    ozmatt Active Member

    Joined:
    Nov 27, 2015
    571
    234
    0
    Location:
    australia
    Vehicle:
    2010 Prius
    Model:
    One
    Thanks tpenny67 will try to quit worrying about it, was just looking for re-assurance that its definitely safe to let spare packs sit dormant almost indefinitely as a few ppl on here have suggested, I do understand that I need to charge them before loading them in any way I just cant get it out of my head that simply letting them sit discharged (for years) will be their death sentance.

    Very interesting thread about the guy with the brand new 05 but so far he has not said if that battery was still good or not, either way if that pack ends up being bad its hard to say if long term storage killed it or being so discharged at the time of spinning the ice for the first time in ten years could well have pulled a cell backwards I guess we will never know
     
  9. dolj

    dolj Senior Member

    Joined:
    May 14, 2012
    7,510
    3,773
    0
    Location:
    Wellington, New Zealand
    Vehicle:
    2007 Prius
    Model:
    N/A
    The fact it spun up the ICE means that it still had >40% charge, otherwise it would have coded.
     
  10. ozmatt

    ozmatt Active Member

    Joined:
    Nov 27, 2015
    571
    234
    0
    Location:
    australia
    Vehicle:
    2010 Prius
    Model:
    One
    naah 40% after 10 years is not really possible even the best module will self discharge a few percent per week after 10 years it seems very unrealistic that it could be anywhere near 40% soc, I would think it was under 10% and thats at best more like just chemical base voltage of 7.2v but effectively 0% soc but the car didn't have a chance to log a code before the battery started to recover once the ice got going, the guy did mention warning lights and red car displayed on the MFD on his very first drive.
     
  11. dolj

    dolj Senior Member

    Joined:
    May 14, 2012
    7,510
    3,773
    0
    Location:
    Wellington, New Zealand
    Vehicle:
    2007 Prius
    Model:
    N/A
    How did the ICE get going with no charge (according to you) in the HV Battery? Remember that as far as the HV ECU is concerned, 40% SOC = discharged. If you drain it less than that (e. g. run out of fuel), it will not spin the ICE.

    If it was under 40% and more like 10% as you state, the car would have just thrown up all the lights and would have been dead in the water. I say again, the fact it fired up means the HV battery had a 40% or great charge.
     
  12. ozmatt

    ozmatt Active Member

    Joined:
    Nov 27, 2015
    571
    234
    0
    Location:
    australia
    Vehicle:
    2010 Prius
    Model:
    One
    I think from what I understand even a "flat" or effectively 0% SOC module will have a couple hundred milliamps sitting at base voltage (7.2v being the lower limit of a "flat" module due to its chemical makeup) that couple hundred mA would be almost enough at 201.6v to spin up the ice just once but it would yank on the modules very hard in doing so, the car monitors for a short time before reporting a code and in that short time the battery has a chance to recover enough to keep the code away. Car can charge at very aggressive rates when it wants to.

    that's my take anyway I could well be wrong, NIMH cells suffer from dramatic amounts of self discharge so I don't understand how after 10 years it could possibly have anywhere near 40% soc ..if I leave a charged module sitting for 4 or 6 months it starts to head down the hill towards 7.2 very rapidly.
     
  13. dolj

    dolj Senior Member

    Joined:
    May 14, 2012
    7,510
    3,773
    0
    Location:
    Wellington, New Zealand
    Vehicle:
    2007 Prius
    Model:
    N/A
    Regardless of all that, which I think is a stretch, the point is that unless there is more than ~215 V (40%) in the hybrid pack, the hybrid control system will not allow the ICE to be spun up. A sort of self preservation, if you like. So what you are postulating can not happen.
    I agree you with you that it is hard to understand, but unless there was some kind of external charging program which was implemented by the previous owner that the OP in that other thread was not aware of (or some other relevant information that has been omitted), the fact remains that there was 40% or more SOC in that HV when he first started it up. As I understand it, with NiMH, there is a relatively high self discharge rate initially, but it tapers off as the battery discharges, so you cannot extrapolate SOC decrease in a linear fashion.
     
  14. ozmatt

    ozmatt Active Member

    Joined:
    Nov 27, 2015
    571
    234
    0
    Location:
    australia
    Vehicle:
    2010 Prius
    Model:
    One
    hi Dolj thanks for replies :) yes I understand discharge is not linear however something still just does not quite ad up when it comes to that car, as you would know 215v is around 7.7 per module, if I leave a 100% soc module on my bench its usually down near 7.4min /7.6max by the next time I look at it.. and that's after a few months not ten years!

    So the question is ..what happens once hibernating modules fall below chemical base voltage, or wont they..

    We shouldn't keep using that particular 2005 car as an example anyway being such a rare situation
     
  15. jeff652

    jeff652 Senior Member

    Joined:
    Feb 6, 2014
    597
    623
    0
    Location:
    Idaho
    Vehicle:
    2005 Prius
    Model:
    II
    Sitting long term and self discharging does not damage NiHM cells. Driving the car after without slowly, fully re-charging the pack and rebalancing the cells is what damages them. The famous "Dog Bite" Citrus Insight that sat in a barn for 15 years and had an excellent IMA Battery after being reconditioned is a perfect example of this:
    Citrus Barn Find in Houston [WIP] - Insight Central: Honda Insight Forum

    I suspect the same positive result would be had on the 2005 Prius with only 200 miles on it if the owner used our products before operating the vehicle. Without slowly recovering the hybrid battery pack and preparing it for a return to service sadly it will not last very long.
     
  16. ozmatt

    ozmatt Active Member

    Joined:
    Nov 27, 2015
    571
    234
    0
    Location:
    australia
    Vehicle:
    2010 Prius
    Model:
    One
    Thanks Jeff its reassuring hearing this from yet another with such extensive experience, Steve has also tried to assure me on more than one occasion that its fine to let them sit I'm a bit of a worry wart! I don't want to waste my spares by simply letting them hibernate a couple years.

    Only thing makes me think twice is the example cars both being barn finds would have exceptionally good modules, as new even..hopefully the theory is not different for matured modules.
     
  17. ozmatt

    ozmatt Active Member

    Joined:
    Nov 27, 2015
    571
    234
    0
    Location:
    australia
    Vehicle:
    2010 Prius
    Model:
    One
    hi all, just wanted to touch on this subject again!

    I recently picked up a 2004 pack that was really flat every module in the pack was under 7v.. must have been sitting for a very long time. Grid charged it at 350mA to 242.48v (y) then a 24 hour rest prior to discharging at 18A ...4 modules tested 5000mA the rest of the pack was around 1000 or less. Cycled the modules 3 times but nothing changed (n)

    Also, this time last year I tested some modules and noted their capacity most were around 5000mA after 24 hour rest so I charged them to 80% for storage, I cycled and retested those modules again this week and most are now 4300-4500 ..

    something is happening to batteries in storage, anyone else having this issue ?

    Matt