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Featured Solid-state battery wars

Discussion in 'Prius, Hybrid, EV and Alt-Fuel News' started by Gokhan, Jan 16, 2021.

  1. royrose

    royrose Senior Member

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    So far QuantumScope has done small prototypes. They have to scale up with multiple layers to have sufficient capacity for an EV. They express confidence that they can do this but they are clear that they haven't done it yet and there may be delays. So their batteries are potentially suitable for EVs.
     
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  2. Gokhan

    Gokhan Senior Member

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    That is correct. Their goal is to hand-make several 8–10-layer all-solid-state battery (ASSB) cells, which roughly have the capacity of an 18650 lithium-ion cell each, by the end of 2021 and then to build 100,000 of them in their prepilot factory QS-0 in San Jose in 2022, which will power about 100 field-test EVs for various OEMs, including their partner Volkswagen/Audi/Porsche Group. If all goes well, they will build their first production factory in 2023, and EVs built with QuantumScape ASSBs should go on sale in 2024.
     
  3. Lee Jay

    Lee Jay Senior Member

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  4. Gokhan

    Gokhan Senior Member

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    See my post before yours. It requires elevated temperatures and pressures; therefore, it is not suitable for EV applications. All-solid-state battery (ASSB) cells that work at elevated temperatures and pressures have been around for decades, and there is nothing groundbreaking about them. Such cells are useless for real-world applications.
     
  5. Lee Jay

    Lee Jay Senior Member

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    And yet, they directly contradicted both of your claims - that it's not suitable for EVs and that it has poor cycle life.
     
  6. Gokhan

    Gokhan Senior Member

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    Samsung's claims on their news release are misleading company propaganda—aka fake news. You can and should read the Nature article to see what their all-solid-state battery (ASSB) is really about, which I did.

    What is "Fake News"? - "Fake News," Lies and Propaganda: How to Sort Fact from Fiction - Research Guides at University of Michigan Library
     
    #66 Gokhan, Mar 1, 2021
    Last edited: Mar 1, 2021
  7. dbstoo

    dbstoo Senior Member

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    When someone starts shouting "Fake News!" it's usually because they can't otherwise discredit a source. I suggest that you quote the specific claims in the article submitted by Samsung and the science that contradicts it. The only corrections that the peer review came up (Mar 20, 2020) with was a slight change in a written formula. I was not inclined to spend $$$ to read the article. The abstract seemed clear enough.

    Exactly what are you complaining about?
    Do you dispute that they expect more than 1000 cycles?
    Are you claiming that they can't reach 900Wh/L ?

    I don't care if it's company propaganda if the main points are valid.
     
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  8. Gokhan

    Gokhan Senior Member

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    I am not contradicting the article. I am contradicting the (fake-)news release, which is contradicting the article. If you have access to the article, you can see that their all-solid-state-battery (ASSB) cell requires elevated temperatures (above 60 °C) and high pressures (above 290 psi (2 MPa)). Therefore, it is not suitable for EV applications. Many companies have made such ASSB cells for decades, but they are not practical to make it to the market. The plaguing problem for ASSB cells has been the lithium-metal dendrites, and for decades the only way to prevent them has been to elevate the temperature and pressure. Currently, QuantumScape is the only company who has discovered a solid-state separator that prevents dendrites at all temperatures and ambient pressure.
     
  9. Trollbait

    Trollbait It's a D&D thing

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    Has QuantumScape published anything in a peer reviewed journal?
     
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  10. Gokhan

    Gokhan Senior Member

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    I don't know, but why should they expose their trade secrets? They have 200 or so patents, more than any other solid-state battery company.
     
  11. Lee Jay

    Lee Jay Senior Member

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    "This statistic shows the top 20 publishers of solid-state battery patents in the U.S. between 2010 and 2019 and the number of patents that were published during this time period. Toyota was the most active in the U.S. for solid-state battery technologies with 203 patents published. That is 5.8 times as many as the next highest number of patents."

    https://www.statista.com/statistics/1008044/us-solid-state-battery-patents-by-organization
     
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  12. Lee Jay

    Lee Jay Senior Member

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    The paper has portions that contradict both of your statements:

    "The cell consisted of ten parallel stacks of the bi-cells and was operated under a 0.05 C (0.34 mA cm−2)/0.05 C (0.34 mA cm−2) charge/discharge rate without external pressure. Notably, we were able to obtain a discharge capacity of 5,870 mAh and a high energy density of 942 Wh l−1 at 100% SOC with this stacked cell."

    "The discharge capacity at 45 °C (99.5%) was comparable to that attained at 60 °C, and the discharge capacity at 25 °C decreased to 90.7%. Encouragingly, more than 40% of the capacity was still exhibited at −10 °C. We believe that the low-temperature performance of the ASSBs can be further improved by further lowering the interfacial resistance and increasing the ion conductivity of the solid electrolyte."
     
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  13. Gokhan

    Gokhan Senior Member

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    Why is QuantumScape not on this list? They say they have over 200 patents.

    EX-99.1
     
  14. Gokhan

    Gokhan Senior Member

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    0.05C = C/20 charge rate, which means 20 hours to full charge is next to nothing. All-solid-state batteries (ASSBs) are supposed to have charge rates as high as 4C (15 minutes to full charge) or more to have an advantage over lithium-ion batteries. It looks like they need high temperature, high pressure, or both, which doesn't impress.
     
  15. Trollbait

    Trollbait It's a D&D thing

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    If they have patents, their secrets would be protected.
     
  16. Lee Jay

    Lee Jay Senior Member

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    If only that were true. But it's not true in reality.
     
  17. Lee Jay

    Lee Jay Senior Member

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    I have 5C charge/40C discharge lithium-ion batteries in my house. But they are under 180Wh/kg. Solid State holds the promise of shifting that tradeoff out - you could have both high energy and high rates at the same time. This one seems to show high energy (higher than high-energy Lithium-Ion) but not high rates, yet.

    As I've said over and over, current batteries suck. If they didn't, we'd all be buying EVs for almost every application.
     
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  18. mikefocke

    mikefocke Prius v Three 2012, Avalon 2011

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    https://patents.justia.com/assignee/quantumscape-corporation contains many pages of patent brief descriptions. Some as recent as January 2021.
     
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  19. hill

    hill High Fiber Member

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    Not quite sure why this thread is called battery "Wars". If you have a bunch of Nations trying to build cannons, is that what we call a war now?
    .
     
    #79 hill, Mar 1, 2021
    Last edited: Mar 2, 2021
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  20. Gokhan

    Gokhan Senior Member

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