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Electro-potential reaction?

Discussion in 'Generation 1 Prius Discussion' started by bwilson4web, Aug 26, 2012.

  1. bwilson4web

    bwilson4web BMW i3 and Model 3

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    There are two competing reactions in NiMH cells:
    • Ni(OH){2} + OH- => NiOOH + H{2}O + e- (300mV):: desirable charge reaction
    • 4OH- => O{2} + 2H{2}O + 4e- (-204mV) :: undesirable O2 generation, deep discharge reaction
    What I remember from chemistry class is the electrons comes with an electromotive force, a voltage, that is needed for each reaction. I suspect the second reaction has a slightly higher voltage requirement BUT I have been too long away from the classroom.

    Would anyone know how to calculate or lookup the electromotive force needed for each reaction?

    Thanks,
    Bob Wilson
     
  2. usnavystgc

    usnavystgc Die Hard DIYer and Ebike enthusiast.

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    Can't help you there Bob. Remember, I'm from KY (lol).